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MAPLES – MAgma PLays with sedimEntary rockS

Med dette prosjektet ønsker vi å få bedre forståelse av prosesser og skaler for forurensning mellom vulkanske lag-ganger og sedimentære vertsbergarter. Prøver fra ulike steder skal samles inn og analyseres for å forstå hva som skjedde da magma varmet opp bergartene de trengte inn i.

Tre feltstudier vil muliggjøre hvordan MAgma PLays with sEdimentary rockS of different lithologies. Feltbildet: Sara Callegaro og Lars Eivind Augland fungerer som skala i bildet. Foto: Ella W. Stokke

Om prosjektet

Tiden vi lever i nå kalles Anthropocene, den menneskelige epoken, fordi menneskelig aktivitet fører til globale endringer i klima og miljø. For å forstå nåtiden studerer vi i MAPLES geologiske hendelser langt tilbake i tid, og som forårsaket lignende endringer på jorda som de vi er vitne til i dag. Hendelser som førte til store konsekvenser for livet på jorda, der mange arter døde ut i raskt tempo i noe man kaller masseutryddelser. Masseutryddelsene sammenfaller ofte med episoder med ekstrem vulkansk aktivitet, også kalt 'store vulkanske provinser' (LIPs), se Wikipedia. Vulkansk aktivitet førte til utslipp av klimagasser (karbondioksid, vanndamp, metan) og giftige gasser (svoveldioksid, forbindelser av klor, fluor eller brom), og i så store mengder at atmosfæren delvis forandret sammensetning.

Hvordan ble disse gassene produsert og sluppet ut til atmosfæren? Magma frakter med seg gasser som stammer fra mantelen (jordas indre), men gass blir også produsert når magma trengte inn i sedimentære bergartslag i jordskorpen og danner horisontale intrusjoner kalt lag-ganger. Det tar lang tid før lag-ganger avkjøles, og når varmen fra lag-gangene treffer bergartslagene, frigjøres gasser og spormetaller. Hvordan interaksjoner mellom magma og sedimentære bergarter foregår er bare delvis kjent.

Les mer om prosjektet på engelske websider.

Mål

Et mål med MAPLES er å forklare hvordan magma, sedimentære bergarter og miljø utveksler elementer og kjemiske forbindelser for å forstå hendelser fra den geologiske fortiden. Bedre kunnskap om hva som skjedde i fortiden, kan muligens representere forklaringer på endringer i klima og miljø vi er vitne til i dag.

Finansiering

Fullt navn for prosjektet er: MAgma PLays with sedimEntary rockS - Element exchange between magma, sedimentary host-rocks and environment. Norsk tittel er Magma vekselvirkning med sedimentære bergarter - element utvelksling mellom magma, sedimentære bergarter og miljø

Finansiering: NFR, FRIPRO – Unge forskertalenter
Prosjekt nummer: 301096 (NFR) | 144995 (UiO)
Start: 15.08.2020. Slutt: 15.01.2024.

Samarbeid

Prosjektet MAPLES vil involvere forskere fra mange institusjoner, og bygger på kunnskap, og langvarig samarbeid mellom forskere fra Universitetet i Oslo, Uppsala (SE), Padova (IT) og McGill (CA). MAPLES vil i tillegg etablere nye samarbeid.

Belosa, Lea; Callegaro, Sara; Meyzen, Christine M; Gaina, Carmen; Polteau, Stephane & Bizimis, Michael [Vis alle 7 forfattere av denne artikkelen] (2024). Deep Mantle Component and Continental Crust Remobilization in the Source of Vesteris Seamount, East Greenland Margin. Geochemistry Geophysics Geosystems. ISSN 1525-2027. 25(1). doi: 10.1029/2023GC011196. Fulltekst i vitenarkiv
Percival, Lawrence M. E.; Matsumoto, Hironao; Callegaro, Sara; Erba, Elisabetta; Kerr, Andrew C. & Mutterlose, Jorg [Vis alle 7 forfattere av denne artikkelen] (2024). Cretaceous Large Igneous Provinces: from volcanic formation to environmental catastrophes and biological crises. Geological Society Special Publication. ISSN 0305-8719. doi: 10.1144/SP544-2023-88. Fulltekst i vitenarkiv
Deegan, Frances M.; Callegaro, Sara; Davies, Joshua H.F.L. & Svensen, Henrik Hovland (2023). Driving Global Change One LIP at a Time. Elements. ISSN 1811-5209. 19(5), s. 269–275. doi: 10.2138/gselements.19.5.269.
Baker, Don R.; Callegaro, Sara; Marzoli, Andrea; De Min, Angelo; Geraki, Kalotina & Whitehouse, Martin, J. [Vis alle 8 forfattere av denne artikkelen] (2023). Sulfur and chlorine in nakhlite clinopyroxenes: Source region concentrations and magmatic evolution. Geochimica et Cosmochimica Acta. ISSN 0016-7037. 359, s. 1–19. doi: 10.1016/j.gca.2023.08.007. Fulltekst i vitenarkiv
Callegaro, Sara; Baker, Don R.; Renne, Paul R.; Melluso, Leone; Geraki, Kalotina & Whitehouse, Martin J. [Vis alle 8 forfattere av denne artikkelen] (2023). Recurring volcanic winters during the latest Cretaceous: Sulfur and fluorine budgets of Deccan Traps lavas. Science Advances. ISSN 2375-2548. 9(40). doi: 10.1126/sciadv.adg8284. Fulltekst i vitenarkiv
Deegan, Frances M.; Bédard, Jean H.; Grasby, Stephen E.; Dewing, Keith; Geiger, Harri & Misiti, Valeria [Vis alle 13 forfattere av denne artikkelen] (2022). Magma-Shale Interaction in Large Igneous Provinces: Implications for Climate Warming and Sulfide Genesis. Journal of Petrology. ISSN 0022-3530. 63(9), s. 1–10. doi: 10.1093/petrology/egac094. Fulltekst i vitenarkiv Vis sammendrag
Large Igneous Provinces (LIPs) whose magma plumbing systems intersect sedimentary basins are linked to upheavals of Earth’s carbon and sulfur cycles and thus climate and life history. However, the underlying mechanistic links between these phenomena are elusive. We address this knowledge gap through short time-scale petrological experiments (1200 °C and 150 MPa) that explore interaction between basaltic melt and carbonaceous shale (mudstone) using starting materials from the Canadian High Arctic LIP and the Sverdrup Basin in which it intrudes. Here we show that entrainment of shale xenoliths in basaltic melt causes shale to shatter due to incipient thermal stress and devolatilization, which accelerates assimilation by increasing reactive surface area. Shale assimilation therefore facilitates transfer of sediment-derived volatile elements to the shallow parts of LIP plumbing systems, whereupon carbon dominates the vapor phase whilst sulfur is partitioned into sulfide melt droplets. This study reveals that although carbon and sulfur are efficiently mobilized as a consequence of shale assimilation, sulfides can sequester sulfur - an important climate cooling agent - thus enhancing net emissions of climate warming greenhouse gases by shale-intersecting LIPs.
Dal Corso, Jacopo; Song, Haijun; Callegaro, Sara; Chu, Daoliang; Sun, Yadong & Hilton, Jason [Vis alle 9 forfattere av denne artikkelen] (2022). Environmental crises at the Permian–Triassic mass extinction. Nature Reviews Earth & Environment. ISSN 2662-138X. 3, s. 197–214. doi: 10.1038/s43017-021-00259-4. Fulltekst i vitenarkiv
Capriolo, Manfredo; Mills, Benjamin J.W.; Newton, Robert J.; Dal Corso, Jacopo; Dunhill, Alexander M. & Wignall, Paul B. [Vis alle 7 forfattere av denne artikkelen] (2022). Anthropogenic-scale CO2 degassing from the Central Atlantic Magmatic Province as a driver of the end-Triassic mass extinction. Global and Planetary Change. ISSN 0921-8181. 209. doi: 10.1016/j.gloplacha.2021.103731. Fulltekst i vitenarkiv
Boscaini, Andrea; Callegaro, Sara; Sun, Yadong & Marzoli, Andrea (2022). Late Permian to Late Triassic Large Igneous Provinces: Timing, Eruptive Style and Paleoenvironmental Perturbations. Frontiers in Earth Science. ISSN 2296-6463. 10. doi: 10.3389/feart.2022.887632. Fulltekst i vitenarkiv
Boscaini, Andrea; Marzoli, A; Bertrand, Hervé; Chiaradia, Massimo; Jourdan, Fred & Faccenda, Manuele [Vis alle 9 forfattere av denne artikkelen] (2022). Cratonic keels controlled the emplacement of the Central Atlantic Magmatic Province (CAMP). Earth and Planetary Science Letters. ISSN 0012-821X. 584. doi: 10.1016/j.epsl.2022.117480.
Capriolo, Manfredo; Marzoli, Andrea; Aradi, László E.; Ackerson, Michael R.; Bartoli, Omar & Callegaro, Sara [Vis alle 12 forfattere av denne artikkelen] (2021). Massive methane fluxing from magma–sediment interaction in the end-Triassic Central Atlantic Magmatic Province. Nature Communications. ISSN 2041-1723. 12. doi: 10.1038/s41467-021-25510-w. Fulltekst i vitenarkiv
Callegaro, Sara; Svensen, Henrik Hovland; Neumann, Else Ragnhild; Polozov, Alexander G.; Jerram, Dougal Alexander & Deegan, Frances M. [Vis alle 10 forfattere av denne artikkelen] (2021). Geochemistry of deep Tunguska Basin sills, Siberian Traps: correlations and potential implications for the end-Permian environmental crisis. Contributions to Mineralogy and Petrology. ISSN 0010-7999. 176. doi: 10.1007/s00410-021-01807-3. Fulltekst i vitenarkiv
Capriolo, Manfredo; Marzoli, Andrea; Aradi, László E.; Callegaro, Sara; Dal Corso, Jacopo & Newton, Robert J. [Vis alle 14 forfattere av denne artikkelen] (2020). Deep CO2 in the end-Triassic Central Atlantic Magmatic Province. Nature Communications. ISSN 2041-1723. 11. doi: 10.1038/s41467-020-15325-6. Fulltekst i vitenarkiv
Lindström, Sofie; Callegaro, Sara; Davies, Joshua H.F.L.; Tegner, Christian; Marzoli, Andrea & van de Schootbrugge, Bas [Vis alle 9 forfattere av denne artikkelen] (2020). Tracing volcanic emissions from the Central Atlantic Magmatic Province in the sedimentary record. Earth-Science Reviews. ISSN 0012-8252. doi: 10.1016/j.earscirev.2020.103444. Fulltekst i vitenarkiv
Baker, Don R.; Callegaro, Sara; De Min, Angelo; Whitehouse, Martin J. & Marzoli, Andrea (2020). Fluorine partitioning between quadrilateral clinopyroxenes and melt. American Mineralogist. ISSN 0003-004X. 107(2), s. 167–177. doi: 10.2138/am-2021-7868. Fulltekst i vitenarkiv

Se alle arbeider i Cristin

Callegaro, Sara (2024). Catch me if you can: reconstructing magmatic volatiles from Large Igneous Provinces with different approaches.
Callegaro, Sara (2024). Large Igneous Provinces: listening to warnings from past volcanoes.
Callegaro, Sara; Baker, Don R.; Renne, Paul R.; Melluso, Leone; Geraki, Kalotina & Whitehouse, Martin J. [Vis alle 8 forfattere av denne artikkelen] (2024). Sulfur and fluorine degassing from Deccan Traps lavas inferred from pyroxene chemistry: potential for end-Cretaceous volcanic winters.
Deegan, Frances M.; Capriolo, Manfredo; Weis, Franz; Callegaro, Sara; Troll, Valentin R. & Freda, Carmela [Vis alle 11 forfattere av denne artikkelen] (2024). Tracking CO2 mobility during magma-limestone interaction: insights from spectroscopic analysis of experiments.
Svensen, Henrik Hovland; Callegaro, Sara; Kjøll, Hans Jørgen; Midtkandal, Ivar; Whattam, Jack William & Dalslåen, Bjørgunn Heggem [Vis alle 10 forfattere av denne artikkelen] (2024). Rhomb porphyry lavas from the Oslo Rift revisited: New insights from construction-related boreholes and cores.
Andersen, Guro Lilledal; Svensen, Henrik Hovland; Augland, Lars Eivind; Callegaro, Sara & Whattam, Jack (2024). The explosive volcanism of the Oslo Rift – insights from the ignimbrites of the Drammen Caldera.
Callegaro, Sara; Svensen, Henrik Hovland; Heimdal, Thea H.; Kjøll, Hans Jørgen; Harstad, Andreas Olaus & Augland, Lars Eivind [Vis alle 9 forfattere av denne artikkelen] (2024). Geochemistry of sills from the early stage of the Oslo Rift.
Capriolo, Manfredo; Callegaro, Sara; Deegan, Frances M.; Merle, Renaud; Jeon, Heejin & Whitehouse, Martin [Vis alle 16 forfattere av denne artikkelen] (2024). The transcrustal plumbing system of Large Igneous Provinces: Insights from glomerocrysts and melt inclusions.
Whattam, Jack; Svensen, Henrik Hovland; Midtkandal, Ivar; Jerram, Dougal Alexander & Callegaro, Sara (2024). Mafic volcaniclastic deposits in the Oslo Rift.
Whattam, Jack; Svensen, Henrik Hovland; Midtkandal, Ivar; Callegaro, Sara & Jerram, Dougal Alexander (2023). Intermittent cessation and renewal of volcanism in the Oslo Rift revealed through detailed mapping and stratigraphy.
Bond, David; Callegaro, Sara; Davies, Joshua; Deegan, Frances; Galloway, Jennifer & Gaynor, Sean [Vis alle 14 forfattere av denne artikkelen] (2023). Meet the Authors. Elements. ISSN 1811-5209. 19(5), s. 265–266. doi: 10.2138/gselements.19.5.265.
Callegaro, Sara; Svensen, Henrik Hovland; Heimdal, Thea Hatlen; Guarino, Vincenza; Deegan, Frances M. & Jerram, Dougal Alexander [Vis alle 8 forfattere av denne artikkelen] (2023). Dolerite sills from the Siberian Traps (Tunguska basin, Russia) bear evidence of halogens mobilization from evaporitic host rocks.
Augland, Lars Eivind; Lundmark, Anders Mattias; Callegaro, Sara & Jerram, Dougal Alexander (2023). Rapid translithospheric ascent rates for Lamprophyres from zircon dissolution speedometry.
Callegaro, Sara; Svensen, Henrik Hovland; Heimdal, Thea Hatlen; Deegan, Frances M.; Jerram, Dougal Alexander & Polozov, Alexander [Vis alle 7 forfattere av denne artikkelen] (2023). Magma-evaporite interaction in doleritic sills from the Siberian Traps: insights from whole-rock and mineral data.
Svensen, Henrik Hovland; John, Timm; Polozov, A.; Callegaro, Sara; Jones, Morgan Thomas & Newton, Robert [Vis alle 8 forfattere av denne artikkelen] (2023). Carbon, sulphur, and mercury geochemistry in a crater lake in the Siberian Traps.
Callegaro, Sara; Whattam, Jack & Svensen, Henrik Hovland (2023). Eruption history through late-stage rift activity: the central volcanoes and caldera-related deposits of the Permian Oslo Rift, southern Norway.
Mariani, Cristina & Callegaro, Sara (2023). K16.
Deegan, Frances M.; Bédard, Jean H.; Grasby, Stephen E.; Dewing, Keith; Geiger, Harri & Misiti, Valeria [Vis alle 13 forfattere av denne artikkelen] (2023). Magma-Shale Interaction and Volatile Mobilization at LIPs: Insights from Kinetic Experiments.
Callegaro, Sara; Dal Corso, Jacopo & Song, Haijun (2023). Editorial: How Large Igneous Provinces (LIPs) during the Triassic shaped modern-day ecosystems. Frontiers in Earth Science. ISSN 2296-6463. 11. doi: 10.3389/feart.2023.1302216. Fulltekst i vitenarkiv
Callegaro, Sara; Svensen, Henrik Hovland; Heimdal, Thea Hatlen; Kjøll, Hans Jørgen; Harstad, Andreas Olaus & Neumann, Else Ragnhild (2022). New insights on shallow intrusions from the early stage of the Oslo Rift. .
Callegaro, Sara; Svensen, Henrik Hovland; Deegan, Frances M.; Planke, Sverre & Polozov, Alexander (2022). Magma-host rock interaction in basaltic sills from the Siberian Traps (Tunguska basin, Russia): mineral scale and whole-rock perspectives.
Boscaini, Andrea; Davies, Joshua H.F.L.; Sassi, Raffaele; Mazzoli, Claudio; Callegaro, Sara & De Min, Angelo [Vis alle 7 forfattere av denne artikkelen] (2022). Lifetime of the Early Permian giant caldera-system of Bolzano/Bozen (North-eastern Italy).
Boscaini, Andrea; Marzoli, Andrea; Bertrand, Hervé; Chiaradia, Massimo; Jourdan, Fred & Faccenda, Manuele [Vis alle 9 forfattere av denne artikkelen] (2022). The architecture of the lithospheric mantle controlled the emplacement of the Central Atlantic Magmatic Province.
Belosa, Lea; Gaina, Carmen; Callegaro, Sara; Mazzini, Adriano; Meyzen, Christine M & Polteau, Stephane [Vis alle 7 forfattere av denne artikkelen] (2022). Plume-Fracture Zone interactions in the NE Atlantic.
Capriolo, Manfredo (2021). "Mass extinction-related CO2 emissions from Earth’s past" .
Capriolo, Manfredo; Callegaro, Sara; Dal Corso, Jacopo; Newton, Robert J.; Baker, Don R. & Renne, Paul R [Vis alle 7 forfattere av denne artikkelen] (2021). Synchrotron light X-ray microtomography reveals a crystalline mush within the deep plumbing system of Large Igneous Provinces.
Belosa, Lea; Gaina, Carmen; Callegaro, Sara; Trønnes, Reidar G; Mazzini, Adriano & Meyzen, Christine M [Vis alle 7 forfattere av denne artikkelen] (2021). Constraining the enigmatic source of Vesteris Seamount volcanism.
Callegaro, Sara; Svensen, Henrik Hovland; Jerram, Dougal Alexander; Neumann, Else Ragnhild; Deegan, Frances M. & Polozov, Alexander [Vis alle 7 forfattere av denne artikkelen] (2021). Geochemistry of low-Ti Siberian Traps sills from the Tunguska Basin bears evidence of magma-crust interaction.
Lindström, Sofie; Callegaro, Sara; Davies, J.; Tegner, Christian; van de Schootbrugge, Bas & Krarup Pedersen, Gunver [Vis alle 9 forfattere av denne artikkelen] (2021). Tracing volcanic emissions from the CAMP volcanism in the sedimentary and biotic record.
Capriolo, Manfredo; Callegaro, Sara; Marzoli, Andrea; Aradi, László E.; Dal Corso, Jacopo & Newton, Robert J. [Vis alle 14 forfattere av denne artikkelen] (2021). Deep CO2 from the Central Atlantic Magmatic Province during the end-Triassic mass extinction.
Baker, Don R.; Callegaro, Sara; Renne, Paul R; De Min, A.; Whitehouse, Martin J. & Marzoli, A (2021). Don’t blame it on Fluorine: Low F concentrations in Deccan Traps magmas straddling the extinction interval estimated from in situ analyses on clinopyroxene.
Callegaro, Sara; Baker, Don R. & Marzoli, Andrea (2021). Quantifying S in silicate melts from their crystal cargo: data and applications.
Callegaro, Sara; Baker, Don R. & Marzoli, Andrea (2021). Quantifying S in silicate melts from their crystal cargo: data and applications. Vis sammendrag
Five volatile species, H2O, CO2, F, Cl, and S, exert their strong control on magmatic systems, but their quantification remains challenging due to their elusive nature. Partitioning between nominally volatile-free minerals and melts was vastly studied for four out of these five volatiles (H2O, CO2, F, and Cl), except sulfur. We here present measurements of sulfur partitioning between clinopyroxene and silicate melts over a range of pressure (0.8-1.2 GPa), temperature (1000-1240°C), and melt composition (49-66 wt% SiO2; Callegaro et al., 2014; 2020).
Callegaro, Sara & Fransson, Line (2021). Frykter flere vulkan-utbrudd og giftig gass. [Avis]. Dagbladet.
Baker, Don R.; Callegaro, Sara; De Min, Angelo; Whitehouse, MJ & Marzoli, Andrea (2020). Fluorine partitioning between quadrilateral clinopyroxenes and melt. Vis sammendrag
Concentrations of fluorine and chlorine were measured by ion-probe in quenched melts (glasses) and coexisting clinopyroxene, orthopyroxene, olivine, and plagioclase in run products of experiments previously used to measure sulfur partitioning between these phases. The partitioning of F between clinopyroxene and silicate melt was determined over a range of pressure, temperature, and melt compositions ranging from basaltic to dacitic (49 to 66 wt.% SiO2) at 0.8 to 1.2 GPa and 1000 to 1240 °C, at hydrous and anhydrous conditions in 13 experiments. Additionally, we determined the crystal-melt partitioning of F for 4 experiments with plagioclase, 2 with orthopyroxene, and 1 with olivine. Although Cl was also measured in the experiments, the concentrations in the crystals are close to measurements in the nominally Cl-free fused silica glass Herasil® and therefore may be at background concentration levels. The partition coefficients of fluorine between clinopyroxene and melt varied from ~0.09 to 0.29 and were linearly dependent upon the concentration of aluminum in the octahedral M1 site of clinopyroxene. Similar relationships were seen in previous studies of the fluorine partition coefficient between clinopyroxene and melt, but no universal relationship that explains all measurements was discovered. These differences are attributed to differing analytical protocols used in the various studies. Nevertheless, we conclude that the self-consistency of each study indicates that F partition coefficients determined using one protocol can be applied to minerals or glasses analyzed using the same protocol to better understand the storage and transport of fluorine in magmatic systems.